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Which of the following concepts can be used to explain the difference in acidity between acetylene (C2H2) and ethylene (C2H4) ?


A) Size
B) Resonance
C) Inductive effect
D) Hybridization

E) A) and C)
F) C) and D)

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Which of the following statements about Lewis bases is true?


A) Lewis bases are electron pair acceptors.
B) Lewis bases are electron pair donors.
C) Lewis bases are proton donors.
D) Lewis bases are proton acceptors.

E) A) and B)
F) None of the above

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Which of the following compounds is the weakest acid?


A) HF
B) HCl
C) HBr
D) HI

E) None of the above
F) A) and B)

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Which of the following statements about Lewis acids is true?


A) Lewis acids are proton donors.
B) Lewis acids are proton acceptors.
C) Lewis acids are electron pair donors.
D) Lewis acids are electron pair acceptors.

E) B) and C)
F) A) and D)

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Which of the following concepts can be used to explain the difference in acidity between acetic acid (CH3COOH) and ethanol (CH3CH2OH) ?


A) Hybridization
B) Electronegativity
C) Resonance
D) Size

E) A) and B)
F) A) and C)

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Consider the following molecule with protons labeled,I-III.Rank these protons in order of decreasing acidity,putting the most acidic first. Consider the following molecule with protons labeled,I-III.Rank these protons in order of decreasing acidity,putting the most acidic first.   A) I > II > III B) I > III > II C) III > II > I D) III > I > II


A) I > II > III
B) I > III > II
C) III > II > I
D) III > I > II

E) None of the above
F) A) and B)

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Which of the following statements about acid strength is true?


A) The stronger the acid,the further the equilibrium lies to the left.
B) The stronger the acid,the smaller the Ka.
C) The stronger the acid,the larger the pKa.
D) The stronger the acid,the smaller the pKa.

E) C) and D)
F) A) and B)

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What is the direction of equilibrium when acetylene (C2H2) reacts with ethoxide (CH3CH2O-) in an acid-base reaction? What is the direction of equilibrium when acetylene (C<sub>2</sub>H<sub>2</sub>) reacts with ethoxide (CH<sub>3</sub>CH<sub>2</sub>O<sup>-</sup>) in an acid-base reaction?   A) Left B) Right C) Neither D) Cannot be determined


A) Left
B) Right
C) Neither
D) Cannot be determined

E) A) and B)
F) A) and C)

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Rank the following conjugate bases in order of increasing basicity,putting the least basic first. Rank the following conjugate bases in order of increasing basicity,putting the least basic first.   A) II < I < III B) II < III < I C) I < II < III D) I < III < II


A) II < I < III
B) II < III < I
C) I < II < III
D) I < III < II

E) B) and C)
F) A) and B)

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Which of the following concepts can be used to explain the difference in acidity between ethanol (CH3CH2OH) and 2-fluoroethanol (FCH2CH2OH) ?


A) Size
B) Inductive effect
C) Resonance
D) Hybridization

E) None of the above
F) A) and B)

Correct Answer

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Which of the following ranks the compounds in order of increasing acidity,putting the least acidic first?


A) CH4 < H2O < NH3
B) H2O < NH3 < CH4
C) NH3 < CH4 < H2O
D) CH4 < NH3 < H2O

E) None of the above
F) A) and B)

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Rank the following compounds in order of increasing acidity,putting the least acidic first. Rank the following compounds in order of increasing acidity,putting the least acidic first.   A) I < IV < III < II B) I < III < IV < II C) II < III < IV < I D) II < IV < III < I


A) I < IV < III < II
B) I < III < IV < II
C) II < III < IV < I
D) II < IV < III < I

E) A) and D)
F) A) and C)

Correct Answer

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Which of the following compounds has the lowest pKa?


A) H2O
B) H2S
C) NH3
D) CH4

E) A) and B)
F) None of the above

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Which is the conjugate base in the following reaction? Which is the conjugate base in the following reaction?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) A) and C)
F) C) and D)

Correct Answer

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Which of the following species is not a Brønsted-Lowry base?


A) BF3
B) NH3
C) H2O
D) PO43-

E) None of the above
F) A) and B)

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Consider the following structures I-IV.Which two species represent constitutional isomers? Consider the following structures I-IV.Which two species represent constitutional isomers?   A) I and II B) I and III C) I and IV D) II and IV


A) I and II
B) I and III
C) I and IV
D) II and IV

E) B) and C)
F) C) and D)

Correct Answer

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Which is the conjugate base in the following reaction? Which is the conjugate base in the following reaction?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) All of the above
F) C) and D)

Correct Answer

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Which of the following statements explains why H2O is a stronger acid than CH4?


A) H2O can form hydrogen bonds while CH4 cannot.
B) H2O forms a less stable conjugate base,HO-.
C) CH4 forms a more stable conjugate base,CH3-.
D) H2O forms a more stable conjugate base,HO-.

E) A) and B)
F) None of the above

Correct Answer

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Which of the following species is the conjugate base of the hydronium ion,H3O+?


A) H3O
B) H2O-
C) H2O
D) HO-

E) None of the above
F) B) and D)

Correct Answer

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Identify the Lewis acid in the following reaction. Identify the Lewis acid in the following reaction.   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) B) and C)
F) C) and D)

Correct Answer

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