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What is the pOH of a 0.0250 M HI solution?


A) 0.944
B) 1.602
C) 12.398
D) 13.056
E) None of these choices are correct.

F) A) and B)
G) A) and C)

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C

What is the pH of a 0.0035 M KOH solution?


A) 2.46
B) 5.65
C) 8.35
D) 11.54
E) None of these choices are correct.

F) B) and C)
G) A) and E)

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Which, if any, of the following is an example of the leveling effect?


A) The concentrations of H+ and OH- in pure water are equal.
B) The number of strong acids equals the number of strong bases.
C) The number of strong acids equals the number of weak acids.
D) In water, no acid stronger than H3O+ can exist.
E) None of these are examples of the leveling effect.

F) None of the above
G) B) and D)

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The substance NaNO3 is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

F) A) and D)
G) D) and E)

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E

When 14.7 mL of aqueous HBr (a strong acid) was added to water, 0.482 L of a solution with a pH of 4.23 was produced. What was the molarity of the original HBr solution?


A) 1.9 × 10-3 M
B) 140 M
C) 0.288 M
D) 0.13 M
E) None of these choices are correct.

F) B) and D)
G) B) and E)

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What is the pH of a 0.0125 M NaOH solution?


A) 0.972
B) 1.903
C) 12.097
D) 13.028
E) None of these choices are correct.

F) B) and C)
G) A) and E)

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All weak acids have strong conjugate bases.

A) True
B) False

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What is the value of Kb for the formate anion, HCOO-? Ka(HCOOH) = 2.1 × 10-4


A) (-2.1 × 10-4)
B) 2.1 × 10-4
C) 6.9 × 10-6
D) 4.8 × 10-11
E) 2.1 × 10-18

F) A) and B)
G) None of the above

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If the compound HX is a strong acid (where H is the acidic proton in this acid), then the ion X- is a weak base.

A) True
B) False

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A solution is prepared by adding 0.10 mol of sodium sulfide, Na2S, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The concentration of sodium ions and sulfide ions will be identical.
E) The concentration of sulfide ions will be greater than the concentration of sodium ions.

F) A) and B)
G) A) and C)

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Select the pair of substances in that an acid is listed followed by its conjugate base.


A) H+, HCl
B) NH3, NH4+
C) HPO42-, H2PO4-
D) HCO3-, CO32-
E) CH3COOH, CH3COOH2+

F) A) and E)
G) D) and E)

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Which of the following is the strongest acid?


A) CH3COOH
B) HF
C) H3PO4
D) H2SO3
E) HI

F) A) and C)
G) A) and B)

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E

What is the [OH-] for a solution at 25°C that has [H3O+] = 2.35 × 10-3 M?


A) 4.26 × 10-5 M
B) 2.35 × 10-11 M
C) 4.26 × 10-12 M
D) 2.35 × 10-17 M
E) None of these choices are correct.

F) C) and E)
G) C) and D)

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Farmers who raise cotton once used arsenic acid, H3AsO4, as a defoliant at harvest time. Arsenic acid is a polyprotic acid with K1 = 2.5 × 10-4, K2 = 5.6 × 10-8, and K3 = 3 × 10-13. What is the pH of a 0.500 M solution of arsenic acid?


A) 0.85
B) 1.96
C) 3.90
D) 4.51
E) None of these choices are correct.

F) None of the above
G) B) and D)

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What is the [OH-] for a solution at 25°C that has pH = 4.29?


A) 1.4 × 10-2 M
B) 5.l × 10-5 M
C) 1.9 × 10-10 M
D) 7.3 × 10-13 M
E) 9.71 M

F) All of the above
G) A) and E)

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In applying molecular orbital theory, the bond order is calculated in the same way as with Lewis structures.

A) True
B) False

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Which of the following is considered a Lewis acid?


A) CH3NH2
B) BCl3
C) F-
D) BF4-
E) CH4

F) A) and B)
G) A) and C)

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What is the [H3O+] for a solution at 25°C that has pOH = 5.640?


A) 2.34 × 10-4 M
B) 2.29 × 10-6 M
C) 4.37 × 10-9 M
D) 4.27 × 10-11 M
E) 8.360 M

F) A) and B)
G) A) and C)

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The acid dissociation constant Ka equals 1.26 × 10-2 for HSO4- and is 5.6 × 10-10 for NH4. Which statement about the following equilibrium is correct? HSO4-(aq) + NH3(aq) The acid dissociation constant K<sub>a</sub> equals 1.26 × 10<sup>-2</sup> for HSO<sub>4</sub><sup>-</sup> and is 5.6 × 10<sup>-10</sup> for NH<sub>4</sub>. Which statement about the following equilibrium is correct? HSO<sub>4-</sub>(aq)  + NH<sub>3</sub>(aq)    SO<sub>4</sub><sup>2-</sup>(aq)  + NH<sub>4</sub><sup>+</sup>(aq)  A)  The reactants will be favored because ammonia is a stronger base than the sulfate anion. B)  The products will be favored because the hydrogen sulfate ion is a stronger acid than the ammonium ion. C)  Neither reactants nor products will be favored because all of the species are weak acids or bases. D)  The initial concentrations of the hydrogen sulfate ion and ammonia must be known before any prediction can be made. E)  This reaction is impossible to predict, since the strong acid and the weak base appear on the same side of the equation. SO42-(aq) + NH4+(aq)


A) The reactants will be favored because ammonia is a stronger base than the sulfate anion.
B) The products will be favored because the hydrogen sulfate ion is a stronger acid than the ammonium ion.
C) Neither reactants nor products will be favored because all of the species are weak acids or bases.
D) The initial concentrations of the hydrogen sulfate ion and ammonia must be known before any prediction can be made.
E) This reaction is impossible to predict, since the strong acid and the weak base appear on the same side of the equation.

F) D) and E)
G) A) and B)

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Given: H2O(aq) + H2O(l) Given: H<sub>2</sub>O(aq)  + H<sub>2</sub>O(l)    H<sub>3</sub>O<sup>+</sup>(aq)  + OH<sup>-</sup>(aq)  ΔH°<sub>rxn</sub> > 0 When the temperature of a sample of pure water is raised above 25°C, A)  the hydronium ion concentration will be greater than the hydroxide ion concentration. B)  the hydronium ion concentration will be less than the hydroxide ion concentration. C)  the value of K<sub>w</sub> will increase. D)  the hydronium ion concentration could change to 1.0 × 10<sup>-</sup><sup>10</sup> M. E)  the hydroxide ion concentration could change to 1.0 × 10<sup>-</sup><sup>10</sup> M. H3O+(aq) + OH-(aq) ΔH°rxn > 0 When the temperature of a sample of pure water is raised above 25°C,


A) the hydronium ion concentration will be greater than the hydroxide ion concentration.
B) the hydronium ion concentration will be less than the hydroxide ion concentration.
C) the value of Kw will increase.
D) the hydronium ion concentration could change to 1.0 × 10-10 M.
E) the hydroxide ion concentration could change to 1.0 × 10-10 M.

F) C) and D)
G) B) and E)

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