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Which of these compounds is a weak electrolyte?


A) HCl
B) NH3
C) C6H12O6 (glucose)
D) N2
E) KCl

F) D) and E)
G) All of the above

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________ ________ is the percentage of dissolved molecules that separate into ions in solution.

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Percent di...

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Which of the following is not a colligative property?


A) Vapor pressure lowering
B) Atmospheric pressure
C) Boiling point elevation
D) Osmotic pressure
E) Freezing point depression

F) A) and E)
G) A) and D)

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Which of the following states that the solubility of a gas in a liquid is proportional to the pressure of the gas over the solution?


A) Entropy
B) Henry's law
C) Dissolution
D) Vapor pressure
E) Enthalpy of solvation

F) A) and B)
G) All of the above

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Sodium hydroxide is a common ingredient in drain cleaners such as Drano®. The mole fraction of sodium hydroxide in a saturated aqueous solution is 0.310. What is the molality of the solution?


A) 0.310 m
B) 0.690 m
C) 1.24 m
D) 12.4 m
E) 24.9 m

F) A) and B)
G) C) and D)

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Which of the following aqueous solutions should demonstrate the most ideal behavior?


A) 0.1 M K2SO4
B) 0.1 M CaCl2
C) 3.0 M LiF
D) 0.1 M MgSO4
E) 0.1 M NaCl

F) A) and E)
G) B) and D)

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What is the name of a solution that obeys Raoult's law?


A) Ideal solution
B) Nonideal solution
C) Suspension
D) Solute
E) Solvent

F) C) and D)
G) A) and D)

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If a 100-mL sample of a volatile liquid such as diethyl ether is introduced into a 250-mL flask which is immediately sealed, the pressure inside will increase above atmospheric pressure. Explain.

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The pressure inside the flask will initially be the same as atmospheric pressure, and the gas present will be air with some ether vapor. Initially, the gas above the liquid will not be saturated with ether vapor. More liquid will evaporate until equilibrium is reached, leading to an increase in pressure.

A solution of chloroform, CHCl3, and acetone, (CH3) 2CO, exhibits a negative deviation from Raoult's law. This result implies that


A) chloroform-chloroform interactions are stronger than chloroform-acetone interactions.
B) chloroform-acetone interactions are weaker than chloroform-chloroform interactions.
C) acetone-acetone interactions are stronger than chloroform-acetone interactions.
D) acetone-acetone interactions are weaker than chloroform-acetone interactions.

E) A) and B)
F) None of the above

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Safrole was once used as a flavoring in root beer, until it was banned in 1960. What is the vapor pressure of a solution prepared by dissolving 0.75 mol of nonvolatile safrole in 950 g of ethanol (46.07 g/mol) ? P°ethanol = 50.0 torr at 25°C.


A) 1.8 torr
B) 11 torr
C) 15 torr
D) 40 torr
E) 48 torr

F) B) and C)
G) C) and E)

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E

What is the molar mass of toluene if 0.85 g of toluene depresses the freezing point of 100. g of benzene by 0.47°C? (Kf of benzene is 5.12°C/m.)


A) 93 g/mol
B) 78 g/mol
C) 10.7 g/mol
D) 82 g/mol
E) 927 g/mol

F) B) and E)
G) All of the above

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Which compound is the most soluble in water?


A) CH3CH2CH2CH2CH2OH
B) CH3CH2CH2CH2OH
C) CH3CH2CH2CH2CH2CH2CH2OH
D) CH3CH2CH2OH
E) All of these compounds are equally soluble in water.

F) A) and C)
G) A) and B)

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A hydrophilic colloid must generally be stabilized.

A) True
B) False

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What is the name of the process in which an ion or a molecule is surrounded by solvent molecules arranged in a specific manner?

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solvation

Calculate the percent by mass of potassium nitrate in a solution made from 45.0 g KNO3 and 295 mL of water at 25ºC. At this temperature, the density of water is 0.997 g/mL.


A) 1.51%
B) 7.57%
C) 13.3%
D) 15.2%
E) 86.7%

F) A) and D)
G) B) and D)

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If a solute dissolves in an endothermic process


A) hydrogen bonds must exist between solvent and solute.
B) strong ion-dipole forces must exist in the solution.
C) the solute must be a gas.
D) the entropy of the solution is immaterial.
E) the entropy of the solution must be greater than that of its pure components.

F) All of the above
G) B) and D)

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________ is the term used for a water loving substance.

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What volume of concentrated (14.7 M) phosphoric acid is needed to prepare 25.0 L of 3.0 M H3PO4?


A) 0.20 L
B) 0.57 L
C) 1.8 L
D) 3.6 L
E) 5.1 L

F) None of the above
G) B) and D)

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Which of the following sets of conditions could exist when two liquids which are completely miscible in one another are mixed?


A) ΔHsoln > 0, entropy of system decreases
B) ΔHsoln ≈ 0, entropy of system decreases
C) ΔHsoln ≈ 0, entropy change of system ≈ 0
D) ΔHsoln ≈ 0, entropy of system increases
E) None of these choices is correct.

F) C) and D)
G) A) and B)

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Which of these compounds is a nonelectrolyte?


A) NaOH
B) HNO3
C) C2H6O (ethanol)
D) KF
E) CH3COOH (acetic acid)

F) B) and D)
G) D) and E)

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