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Which substance will exhibit hydrogen bonding between molecules?


A) (CH3) 3N
B) CH3-O-CH3
C) CH3CH2-OH
D) CH3CH2-F
E) HI

F) A) and E)
G) D) and E)

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Which of the following lacks a regular three-dimensional arrangement of atoms?


A) crystalline solid
B) ionic crystal
C) solid
D) amorphous solid
E) molecular solid

F) None of the above
G) A) and C)

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What is the energy in kJ/mol required to melt 1 mole of a solid?


A) molar heat of freezing
B) molar heat of fission
C) molar heat of vaporization
D) molar heat of fusion
E) molar heat of condensation

F) C) and E)
G) A) and C)

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The energy of a hydrogen bond is greater than that of a typical covalent bond.

A) True
B) False

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Identify the dominant (strongest) type of intermolecular force present in NH3(l).

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Give an example of an ionic crystal and a metallic crystal which contain an element common to each.

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NaCl = ion...

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Which statement is true about phase diagrams?


A) The triple point pressure is always found below 1 atmosphere.
B) The slope of the liquid-solid phase boundary line is typically negative.
C) The triple point temperature is the lowest temperature where a liquid can exist.
D) The critical temperature is lower than the triple point temperature.
E) The critical temperature is lower than the normal boiling point.

F) A) and B)
G) D) and E)

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The number of atoms in a body-centered cubic unit cell is


A) 1.
B) 2.
C) 3.
D) 4.
E) 8.

F) C) and D)
G) A) and C)

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The number of atoms in a face-centered cubic unit cell is


A) 1.
B) 2.
C) 3.
D) 4.
E) 8.

F) A) and B)
G) None of the above

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The location that indicates conditions under which two phases can exist in equilibrium is called the


A) triple point.
B) critical point.
C) phase boundary.
D) phase diagram.
E) transition state.

F) B) and E)
G) B) and D)

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Iron crystallizes in the body-centered cubic lattice. What is the coordination number for Fe?


A) 4
B) 6
C) 8
D) 10
E) 12

F) C) and D)
G) A) and B)

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The strongest intermolecular interactions between hydrogen fluoride (HF) molecules arise from


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) ion-dipole interactions.
E) ionic bonds.

F) B) and E)
G) None of the above

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Which arrow represents the process of vaporization?


A) Which arrow represents the process of vaporization? A)    B)    C)    D)    E)
B) Which arrow represents the process of vaporization? A)    B)    C)    D)    E)
C) Which arrow represents the process of vaporization? A)    B)    C)    D)    E)
D) Which arrow represents the process of vaporization? A)    B)    C)    D)    E)
E) Which arrow represents the process of vaporization? A)    B)    C)    D)    E)

F) D) and E)
G) B) and D)

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The atomic planes in a graphite crystal are separated by 335 pm. At what angle would you find the first-order (n = 1) diffraction of 0.154-nm X rays from a graphite crystal?


A) 27.4°
B) 66.8°
C) 0.232°
D) 13.3°
E) 38.0°

F) A) and D)
G) A) and E)

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Which one of the following substances crystallizes as a molecular solid?


A) KI
B) SiO2
C) Sn
D) CH3OH
E) Al2(SO4) 3

F) A) and C)
G) B) and C)

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Variable melting point, variable hardness, and good conductor of heat and electricity are properties which describe a(n) ________ crystal.

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In the packing of identical atoms with cubic unit cells, the packing efficiency increases as the coordination number increases.

A) True
B) False

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________ ________ is a special type of dipole-dipole interaction.

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Use the graph of vapor pressure to determine the normal boiling point of O2. Use the graph of vapor pressure to determine the normal boiling point of O<sub>2</sub>.   A)  92 K B)  90. K C)  88 K D)  84 K E)  78 K


A) 92 K
B) 90. K
C) 88 K
D) 84 K
E) 78 K

F) A) and B)
G) A) and E)

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Which substance has the highest vapor pressure at room temperature?


A) HF
B) HCl
C) HBr
D) HI
E) All of these substances have the same vapor pressure at room temperature.

F) A) and E)
G) A) and C)

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