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Which one of the following indoor air pollutants has adverse health effects because it is radioactive


A) formaldehyde
B) carbon monoxide
C) carbon dioxide
D) radon

E) A) and B)
F) B) and D)

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The steps in the mechanism of ozone destruction by chlorine atoms is shown here: Cl2(g) + O3(g) \rarr 2ClO(g) + O2(g) ClO(g) + O(g) \rarr O2(g) + Cl(g)

A) True
B) False

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A possible reaction leading to removal of ClO from the atmosphere is 2ClO \rarr Cl2 + O2. Studies of this reaction have yielded an Arrhenius frequency factor (A) and activation energy of 1.0 * 10-12 cm3 molecule-1 s-1 and 13.2 kJ/mol, respectively. Calculate the rate constant for the disappearance of ClO at -30 \circ C.


A) 1.5 * 10-15 M-1 s-1
B) 8.7 * 105 M-1 s-1
C) 2.9 * 10-15 M-1 s-1
D) 9.9 * 10-13 M-1 s-1
E) 1.7 * 106 M-1 s-1

F) B) and C)
G) C) and D)

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Which of the following is a promising candidate as an alternative to using chlorofluorocarbons as a coolant


A) CCl2F2
B) CClF3
C) CFCl3
D) CH2FCF3
E) C3H8

F) A) and D)
G) A) and C)

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The mechanism for the decomposition of ozone in the presence of a reactive chlorine atom is shown below. Which of the following species is an intermediate O3 + (UV light) \rarr O + O2 Cl + O3 \rarr ClO + O2 ClO + O \rarr Cl + O2


A) Cl
B) ClO
C) O3
D) O2
E) UV light

F) A) and B)
G) C) and D)

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Which region of the atmosphere contains the ozone layer


A) thermosphere
B) mesosphere
C) stratosphere
D) troposphere

E) A) and D)
F) None of the above

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List the following greenhouse gases in order of their overall magnitude of contribution to global warming: N2O, CFCs, CO2, CH4.


A) N2O < CFCs < CO2 < CH4
B) N2O < CH4 < CFCs < CO2
C) CO2 < N2O < CFCs < CH4
D) CH4 < CFCs < N2O < CO2
E) N2O < CFCs < CH4 < CO2

F) B) and D)
G) All of the above

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Of the following which one, if any, is not one of the primary pollutants removed from automobile exhaust by catalytic converters.


A) CO
B) CO2
C) NO
D) Unburned hydrocarbons
E) All of the above are removed from automobile exhaust through catalytic converters

F) C) and D)
G) A) and B)

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Which one of the following is not a greenhouse gas


A) H2O
B) O2
C) CO2
D) CH4
E) CFCs

F) B) and C)
G) All of the above

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An unusual atmospheric reaction leading to ozone destruction is CF3O + O3 \rarr CF3O2 + O2, the analysis of which has yielded an Arrhenius frequency factor (A) and activation energy of 2.0 * 10-12 cm3 molecule-1 s-1 and 11.6 kJ/mol, respectively. Calculate the rate constant for this reaction at an altitude of 35 km, where the temperature is -34 \circ C.


A) 2.0 * 10-12 M-1 s-1
B) 1.2 * 109 M-1 s-1
C) 3.5* 106 M-1 s-1
D) 7.9 * 10-15 M-1 s-1
E) 6.8 * 108 M-1 s-1

F) A) and E)
G) A) and D)

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Select all of the following that are capable of destroying stratospheric ozone through chemical means I. CF2Cl2 II. NO III. CO2


A) I, II, and III
B) I and III
C) II and III
D) I and II
E) I only

F) A) and B)
G) C) and D)

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The mechanism for the decomposition of ozone in the presence of a reactive chlorine atom is shown below. Which species functions as a catalyst O3 + (UV light) \rarr O + O2 Cl + O3 \rarr ClO + O2 ClO + O \rarr Cl + O2


A) O
B) Cl
C) ClO
D) CFCl3
E) O2

F) A) and D)
G) B) and C)

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Which of the following would NOT help reduce the amount of CO2 introduced into the atmosphere


A) Improving energy efficiency in automobiles
B) Use of nuclear energy
C) Recover methane gas generated at landfills
D) Preservation of the Amazon jungle
E) Converting forests to farmland for crops and grassland for cattle

F) All of the above
G) B) and C)

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An increase in the amount of particulate matter (dust and smoke) in the atmosphere may result in cooler world temperatures because


A) more sunlight is absorbed by Earth.
B) more infrared radiation is emitted into space.
C) the dust reflects solar radiation.
D) dust reacts with ozone in an exothermic reaction.

E) None of the above
F) A) and C)

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The ozone layer in the atmosphere protects animals and plants from


A) infrared radiation.
B) acid rain.
C) visible sunlight.
D) radioactivity.
E) ultraviolet rays.

F) A) and E)
G) B) and E)

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Which statement about ozone and the ozone layer is true


A) Ozone is found in a band of almost pure ozone several kilometers thick encircling the Earth.
B) The ozone in the ozone layer absorbs UV light between 200 and 300 nm.
C) Ozone is a compound with the chemical formula CO2.
D) In the Earth's atmosphere, ozone exists only in the ozone layer.
E) Ozone is used as a coolant in refrigerators and air conditioners.

F) C) and D)
G) A) and E)

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B

Which of the following reactions associated with nitrogen fixation by lightening is a disproportionation reaction I. N2(g) + O2(g) \rarr 2NO(g) II. 2NO(g) + O2(g) \rarr 2NO2(g) III. 2NO2(g) + H2O(l) \rarr HNO2(aq) + HNO3(aq)


A) I, II, and III
B) II and III
C) I and II
D) I and III
E) III only

F) A) and B)
G) None of the above

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E

Shown here are the four steps that show how sulfur in coal is converted to sulfuric acid in acid rain. Which step, if any, shows an unbalanced equation


A) S(s) + O2(g) \rarr SO2(g)
B) SO2(g) + OH(g) \rarr HOSO2(g)
C) HOSO2(g) + O2 \rarr HO2(g) + SO3(g)
D) SO3(g) + H2O(l) \rarr H2SO4(aq)
E) None of the above are unbalanced equations

F) C) and D)
G) B) and D)

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The steps in the reaction scheme for nitrogen fixation by lightening are as follow: N2(g) + O2(g)      lightening     \underrightarrow{~~~~\text { lightening }~~~~} 2NO(g) 2NO(g) + O2(g) \rarr 2NO2(g) 2NO2(g) + H2O(l) \rarr HNO2(aq) + HNO3(aq)

A) True
B) False

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In order for a gas to be a "greenhouse gas" it must


A) transmit visible light and absorb infrared radiation.
B) be radioactive.
C) transmit infrared light and absorb visible light.
D) be combustible.
E) absorb both visible light and infrared radiation.

F) A) and E)
G) A) and D)

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A

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