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Consider the dissolution of MnS in water (Ksp = 3.0 ×\times 10-14) . MnS(s) + H2O(l)  Consider the dissolution of MnS in water (K<sub>sp</sub> = 3.0  \times  10<sup>-14</sup>) . MnS(s) + H<sub>2</sub>O(l)    Mn<sup>2+</sup>(aq) + HS<sup>-</sup>(aq) + OH<sup>-</sup>(aq)  How is the solubility of manganese(II) sulfide affected by the addition of aqueous potassium hydroxide to the system? A) The solubility will be unchanged. B) The solubility will decrease. C) The solubility will increase. D) The amount of KOH added must be known before its effect can be predicted. E) The pK<sub>a</sub> of H<sub>2</sub>S is needed before a reliable prediction can be made. Mn2+(aq) + HS-(aq) + OH-(aq) How is the solubility of manganese(II) sulfide affected by the addition of aqueous potassium hydroxide to the system?


A) The solubility will be unchanged.
B) The solubility will decrease.
C) The solubility will increase.
D) The amount of KOH added must be known before its effect can be predicted.
E) The pKa of H2S is needed before a reliable prediction can be made.

F) B) and D)
G) A) and D)

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Hydrofluoric acid (HF)has a Ka value of 7.2 ×\times 10-4. a.0.250 mol of F- ions (in the form of NaF)are added to 1.00 L of 0.100 mol L-1 aqueous HF.Calculate the resulting pH. b.To the solution produced in (a)is added 10.0 mL of 5.00 mol L-1 NaOH.Calculate the resulting pH.

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Which of the following substances has the greatest solubility in water?


A) MgCO3,Ksp = 3.5 ×\times 10-8
B) NiCO3,Ksp = 1.3 ×\times 10-7
C) AgIO3,Ksp = 3.1 ×\times 10-8
D) CuBr,Ksp = 5.0 ×\times 10-9
E) AgCN,Ksp = 2.2 ×\times 10-16

F) All of the above
G) B) and E)

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A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH.The following data were collected during the titration.  A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH.The following data were collected during the titration.   What is the K<sub>a</sub> for HClO? A) 1.1  \times  10<sup>-7</sup> B) 3.5  \times  10<sup>-8</sup> C) 1.2  \times  10<sup>-8</sup> D) 4.9  \times  10<sup>-11</sup> E) None of these choices is correct. What is the Ka for HClO?


A) 1.1 ×\times 10-7
B) 3.5 ×\times 10-8
C) 1.2 ×\times 10-8
D) 4.9 ×\times 10-11
E) None of these choices is correct.

F) A) and D)
G) A) and E)

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A buffer is prepared by adding 1.00 L of 1.0 M HCl to 750 mL of 1.5 M NaHCOO.What is the pH of this buffer? Ka = 1.7 ×\times 10-4


A) 2.87
B) 3.72
C) 3.82
D) 3.95
E) 4.66

F) C) and D)
G) A) and E)

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A lab technician adds 0.015 mol of KOH to 1.00 L of 0.0010 M Ca(NO3) 2.Ksp = 6.5 ×\times 10-6 for Ca(OH) 2.Which of the following statements is correct?


A) Calcium hydroxide precipitates until the solution is saturated.
B) The solution is unsaturated and no precipitate forms.
C) The concentration of calcium ions is reduced by the addition of the hydroxide ions.
D) One must know Ksp for calcium nitrate to make meaningful predictions on this system.
E) The presence of KOH will raise the solubility of Ca(NO3) 2.

F) A) and E)
G) A) and D)

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Equal volumes of the following pairs of solutions are mixed.Which pair will produce a buffer solution?


A) 0.10 mol L-1 HCl and 0.05 mol L-1 NaOH
B) 0.10 mol L-1 HCl and 0.15 mol L-1 NH3
C) 0.10 mol L-1 HCl and 0.05 mol L-1 NH3
D) 0.10 mol L-1 HCl and 0.20 mol L-1 CH3COOH
E) 0.10 mol L-1 HCl and 0.20 mol L-1 NaCl

F) A) and C)
G) A) and E)

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The solubility of lead(II) chloride is 0.45 g/100 mL of solution.What is the Ksp of PbCl2?


A) 4.9 ×\times 10-2
B) 1.7 ×\times 10-5
C) 8.5 ×\times 10-6
D) 4.2 ×\times 10-6
E) < 1.0 ×\times 10-6

F) C) and D)
G) C) and E)

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Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak base (0.10 mol L-1) with HCl of the same concentration?


A)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak base (0.10 mol L<sup>-1</sup>) with HCl of the same concentration? A)    B)    C)    D)    E)
B)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak base (0.10 mol L<sup>-1</sup>) with HCl of the same concentration? A)    B)    C)    D)    E)
C)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak base (0.10 mol L<sup>-1</sup>) with HCl of the same concentration? A)    B)    C)    D)    E)
D)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak base (0.10 mol L<sup>-1</sup>) with HCl of the same concentration? A)    B)    C)    D)    E)
E)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak base (0.10 mol L<sup>-1</sup>) with HCl of the same concentration? A)    B)    C)    D)    E)

F) A) and D)
G) A) and B)

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Calculate the solubility of silver oxalate,Ag2C2O4,in pure water.Ksp = 1.0 ×\times 10-11


A) 1.4 ×\times 10-4 M
B) 8.2 ×\times 10-5 M
C) 5.4 ×\times 10-5 M
D) 3.2 ×\times 10-6 M
E) 2.5 ×\times 10-12 M

F) A) and C)
G) B) and E)

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A 25.0-mL sample of 0.35 M HCOOH is titrated with 0.20 M KOH.What is the pH of the solution after 25.0 mL of KOH has been added to the acid? Ka = 1.77 ×\times 10-4


A) 4.00
B) 3.88
C) 3.63
D) 3.51
E) 3.47

F) C) and E)
G) None of the above

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Make a clear distinction between buffer range and buffer capacity.

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Buffer range is the range of pH over whi...

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Calculate the solubility of zinc hydroxide,Zn(OH) 2,in 1.00 M NaOH. Ksp = 3.0 ×\times 10-16 for Zn(OH) 2,Kf = 3.0 ×\times 1015 for Zn(OH) 42-


A) 0.60 M
B) 0.52 M
C) 0.37 M
D) 0.32 M
E) 0.24 M

F) A) and D)
G) A) and E)

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The equivalence point in a titration is defined as the point when the indicator changes color.

A) True
B) False

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A CH3COOH/CH3COO- buffer can be produced by adding a strong acid to a solution of CH3COO- ions.

A) True
B) False

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Silver phosphate,Ag3PO4,is an ionic compound with a solubility product constant Ksp of 2.6 ×\times 10-18.Calculate the solubility of this compound in a.pure water. b.0.20 mol L-1 Na3PO4 solution.

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a.1.8 blured image 10-5

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What is the pKa for the acid HA if a solution of 0.65 M HA and 0.85 M NaA has a pH of 4.75?


A) < 4.00
B) 4.63
C) 4.87
D) 5.02
E) > 5.50

F) A) and B)
G) C) and E)

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A solution is prepared by adding 4.50 mol of sodium hydroxide to 1.00 L of 1.00 M Co(NO3) 2.What is the equilibrium concentration of cobalt ions? Kf = 5.0 ×\times 109 for Co(OH) 42-


A) 1.1 ×\times 10-2 M
B) 1.4 ×\times 10-5 M
C) 3.2 ×\times 10-9 M
D) 2.0 ×\times 10-10 M
E) 4.9 ×\times 10-13 M

F) B) and D)
G) A) and D)

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Buffer solutions with the component concentrations shown below were prepared.Which of them should have the highest pH?


A) [H2PO4-] = 0.50 M,[HPO42-] = 0.50 M
B) [H2PO4-] = 1.0 M,[HPO42-] = 1.0 M
C) [H2PO4-] = 1.0 M,[HPO42-] = 0.50 M
D) [H2PO4-] = 0.50 M,[HPO42-] = 1.0 M
E) [H2PO4-] = 0.75 M,[HPO42-] = 1.0 M

F) All of the above
G) B) and E)

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What is the [H3O+] in a solution that consists of 1.2 M HClO and 2.3 M NaClO? Ka = 3.5 ×\times 10-8


A) 7.8 ×\times 10-9 M
B) 1.8 ×\times 10-8 M
C) 6.7 ×\times 10-8 M
D) 1.6 ×\times 10-7 M
E) None of these choices is correct.

F) C) and D)
G) A) and E)

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