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A 3.0-L sample of helium was placed in a container fitted with a porous membrane. Half of the helium effused through the membrane in 24 hours. A 3.0-L sample of oxygen was placed in an identical container. How many hours will it take for half of the oxygen to effuse through the membrane?


A) 8.5 h
B) 12 h
C) 48 h
D) 60. h
E) 68 h

F) A) and D)
G) C) and D)

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For a pure gas sample, the average kinetic energy is also the most probable kinetic energy.

A) True
B) False

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Briefly state the conditions corresponding to STP (standard temperature and pressure).

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At STP, the pressure...

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A sample of propane, a component of LP gas, has a volume of 35.3 L at 315 K and 922 torr. What is its volume at STP?


A) 25.2 L
B) 30.6 L
C) 33.6 L
D) 37.1 L
E) 49.2 L

F) D) and E)
G) All of the above

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Which of the lines on the figure below is the best representation of the relationship between the volume and the number of moles of a gas, measured at constant temperature and pressure? Which of the lines on the figure below is the best representation of the relationship between the volume and the number of moles of a gas, measured at constant temperature and pressure?

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A 0.850-mole sample of nitrous oxide, a gas used as an anesthetic by dentists, has a volume of 20.46 L at 123°C and 1.35 atm. What would be its volume at 468°C and 1.35 atm?


A) 5.38 L
B) 10.9 L
C) 19.0 L
D) 38.3 L
E) 77.9 L

F) D) and E)
G) C) and E)

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Calculate the root-mean-square speed of methane, CH4 (g) , at 78°C.


A) 23 m/s
B) 350 m/s
C) 550 m/s
D) 667 m/s
E) 740 m/s

F) B) and E)
G) A) and C)

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The volume of a single molecule of water is 2.99 × 10-23 mL. For a sample of gaseous water at 1.00 atm and 150 °C, what fraction of the container's volume is occupied by the molecules themselves?


A) 5.2 × 10-7
B) 4.5 × 10-5
C) 5.2 × 10-4
D) 5.2 × 10-1
E) none of the above

F) A) and B)
G) A) and C)

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At what temperature in kelvin is the root mean square speed of helium atoms (atomic weight = 4.00) equal to that of oxygen molecules (molecular weight = 32.00) at 300. K?


A) 37.5 K
B) 75 K
C) 106 K
D) 292 K
E) 2400. K

F) C) and D)
G) B) and D)

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At a temperature of absolute zero, the volume of an ideal gas is zero.

A) True
B) False

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Assuming ideal behavior, what is the density of argon gas at STP, in g/L?


A) 0.0176 g/L
B) 0.0250 g/L
C) 0.0561 g/L
D) 1.78 g/L
E) 181. g/L

F) C) and D)
G) A) and B)

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According to the postulates of kinetic-molecular theory, the molecules of all gases at a given temperature have the same average speed.

A) True
B) False

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The temperature of the carbon dioxide atmosphere near the surface of Venus is 475°C. Calculate the average kinetic energy per mole of carbon dioxide molecules on Venus.


A) 2520 J/mol
B) 4150 J/mol
C) 5920 J/mol
D) 9330 J/mol
E) 5920 kJ/mol

F) C) and E)
G) B) and C)

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A 3.60-L gas sample is at a pressure of 95.5 kPa and a temperature of 25.0°C. a. Calculate the volume occupied by the gas at STP, assuming it behaves ideally. b. If the gas sample weighs 6.10 g, calculate the molar mass of the gas.

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a. 3.11 L
...

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A sample of nitrogen gas is confined to a 14.0 L container at 375 torr and 37.0°C. How many moles of nitrogen are in the container?


A) 0.271 mol
B) 2.27 mol
C) 3.69 mol
D) 206 mol
E) 227 mol

F) D) and E)
G) C) and E)

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"The volume of an ideal gas is directly proportional to its absolute temperature at constant pressure and number of moles" is a statement of ________________ Law.


A) Charles's
B) Boyle's
C) Amontons's
D) Avogadro's
E) Dalton's

F) A) and B)
G) C) and D)

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Lithium oxide is an effective absorber of carbon dioxide and can be used to purify air in confined areas such as space vehicles. What volume of carbon dioxide can be absorbed by 1.00 kg of lithium oxide at 25°C and 1.00 atm? Li2O(aq) + CO2(g) Li2CO3(s)


A) 687 mL
B) 819 mL
C) 687 L
D) 819 L
E) 22.4 L

F) A) and D)
G) C) and D)

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Calculate the temperature of an argon sample at 55.4 kPa and 18.6 L if it occupies 25.8 L at 75.0°C and 41.1 kPa.


A) 95.0°C
B) 85.1°C
C) 77.2°C
D) 72.9°C
E) 65.2°C

F) A) and E)
G) D) and E)

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Nitrogen dioxide is a red-brown gas that is responsible for the color of photochemical smog. A sample of nitrogen dioxide has a volume of 28.6 L at 45.3°C and 89.9 kPa. What is its volume at STP?


A) 21.8 L
B) 27.6 L
C) 29.6 L
D) 37.6 L
E) 153 L

F) B) and E)
G) D) and E)

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Given that pressure has dimensions of force ÷ area; that force has dimensions of mass × acceleration; and that the S.I. unit of pressure is the pascal, what is 1 pascal in terms of S.I. base units?


A) 1 Pa = 1000 g/cms2
B) 1 Pa = 1 g/ms2
C) 1 Pa = 10-3 kgm/s2
D) 1 Pa = 1 kgm/s2
E) 1 Pa = 1 kg/ms2

F) A) and B)
G) A) and C)

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