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Consider the following adjectives used to describe types of spectrum: continuous line atomic emission absorption How many of them are appropriate to describe the spectrum of radiation given off by a black body?


A) none
B) one
C) two
D) three
E) four

F) C) and E)
G) D) and E)

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What is the minimum uncertainty in the position of a neutron if the uncertainty in its speed is 0.0250 m/s?

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The Rydberg equation is an example of an empirical equation.

A) True
B) False

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In the quantum mechanical treatment of the hydrogen atom, the probability of finding an electron at any point is proportional to the wave function .

A) True
B) False

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a. Use the Bohr equation to calculate the energy needed to ionize a hydrogen atom from its ground state. b. What is the minimum wavelength of a photon needed for it to have the energy needed in (a)?

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a. 2.18 × ...

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In an atom, the square of an electron's wave function


A) becomes zero at the nucleus.
B) is smallest near the nucleus.
C) is largest near the nucleus.
D) may be zero at more than one point.
E) tends to infinity at large distances from the nucleus.

F) None of the above
G) A) and E)

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For potassium metal, the work function (the minimum energy needed to eject an electron from the metal surface) is 3.68 × 10-19 J. Which is the longest wavelength of the following which could excite photoelectrons?


A) 550. nm
B) 500. nm
C) 450. nm
D) 400. nm
E) 350. nm

F) C) and E)
G) A) and E)

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In the quantum mechanical treatment of the hydrogen atom, the energy depends on the principal quantum number n but not on the values of l or ml.

A) True
B) False

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The interference pattern seen when light passes through narrow, closely spaced slits, is due to


A) diffraction.
B) reflection.
C) refraction.
D) dispersion.
E) deflection.

F) D) and E)
G) C) and D)

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A photon has an energy of 5.53 × 10-17 J. What is its frequency in s-1?


A) 3.66 × 10-50 s-1
B) 1.20 × 10-17 s-1
C) 3.59 × 10-9 s-1
D) 2.78 × 108 s-1
E) 8.35 × 1016 s-1

F) C) and E)
G) All of the above

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Continuous spectra are characteristic of heated solids.

A) True
B) False

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For all the allowed vibration(s) (wavelength(s) ) of a plucked guitar string, what is the correct relationship between the length of the string, L, and the wavelength, ?


A) L = /2
B) L =
C) L = n/2 where n is a positive integer
D) L = n where n is a positive integer
E) L = 1/

F) A) and B)
G) D) and E)

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The size of an atomic orbital is associated with


A) the principal quantum number (n) .
B) the angular momentum quantum number (l) .
C) the magnetic quantum number (ml) .
D) the spin quantum number (ms) .
E) the angular momentum and magnetic quantum numbers, together.

F) C) and D)
G) A) and C)

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What is the speed of an electron in m/s if its wavelength is 0.155 nm?

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The AM station KBOR plays your favorite music from the 20's and 30's at 1290 kHz. Find the wavelength of these waves.


A) 4.30 × 10-2 m
B) 0.144 m
C) 6.94 m
D) 232 m
E) > 103 m

F) None of the above
G) D) and E)

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A radio wave has a frequency of 8.6 × 108 Hz. What is the energy of one photon of this radiation?


A) 7.7 × 10-43 J
B) 2.3 × 10-34 J
C) 5.7 × 10-25 J
D) 1.7 × 10-16 J
E) > 10-15 J

F) A) and B)
G) A) and C)

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Green light has a wavelength of 5200 Å. Calculate the energy of one photon of green light.


A) 3.4 × 10-40 J
B) 3.4 × 10-30 J
C) 3.8 × 10-29 J
D) 3.4 × 10-27 J
E) 3.8 × 10-19 J

F) None of the above
G) B) and C)

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Electromagnetic radiation can be specified by its wavelength () , its frequency () or its period () . The period is the time it takes one complete wavelength to pass a point in space. Based on this information, what is the mathematical relationship between and ?


A) ( = 1/)
B) ( = )
C) ( = /c)
D) c = x
E) ( = c/)

F) A) and D)
G) D) and E)

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In the quantum mechanical treatment of the hydrogen atom, the functions and 2 both feature prominently. Briefly explain (in principle) how they are obtained and what, if anything, their physical meanings are.

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The wave function, , is ...

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What are the possible values for the following quantum numbers in an atom? a. n b. l c. ml

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a. n = 1, 2, 3, ...

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