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The solubility of gases in water increases with increase in the pressure of the gas.

A) True
B) False

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A 0.100 m MgSO4 solution has a freezing point of -0.23°C. What is the van't Hoff factor for this solution? Kf = 1.86°C/m


A) 0.62
B) 1.0
C) 1.2
D) 2.0
E) 4.0

F) D) and E)
G) B) and C)

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In general, water is a good solvent for both polar and non-polar compounds.

A) True
B) False

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Procaine hydrochloride ( Procaine hydrochloride (   = 272.77 g/mol)  is used as a local anesthetic. Calculate the molarity of a 4.666 m solution which has a density of 1.1066 g/mL. A)  2.272 M B)  4.056 M C)  4.216 M D)  4.666 M E)  none of the above = 272.77 g/mol) is used as a local anesthetic. Calculate the molarity of a 4.666 m solution which has a density of 1.1066 g/mL.


A) 2.272 M
B) 4.056 M
C) 4.216 M
D) 4.666 M
E) none of the above

F) B) and C)
G) None of the above

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Select the type of interaction which best describes the attraction between Mg2+ ions and water molecules.


A) dipole-dipole
B) dipole-induced dipole
C) ion-dipole
D) ion-induced dipole
E) ion-hydrogen bond

F) A) and B)
G) None of the above

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Select the strongest electrolyte from the following set.


A) CH3CH2OH, ethanol
B) LiNO3
C) C6H12O6, glucose
D) CCl4
E) HF

F) B) and C)
G) A) and B)

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An emulsion is a dispersion consisting of a


A) solid in a liquid.
B) liquid in a liquid.
C) gas in a liquid.
D) liquid in a solid.
E) gas in a solid.

F) A) and B)
G) D) and E)

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Calculate the vapor pressure of a solution prepared by dissolving 0.500 mol of a non-volatile solute in 275 g of hexane ( Calculate the vapor pressure of a solution prepared by dissolving 0.500 mol of a non-volatile solute in 275 g of hexane (   = 86.18 g/mol)  at 49.6°C. P°<sub>hexane</sub> = 400.0 torr at 49.6°C. A)  54 torr B)  154 torr C)  246 torr D)  346 torr E)  400. torr = 86.18 g/mol) at 49.6°C. P°hexane = 400.0 torr at 49.6°C.


A) 54 torr
B) 154 torr
C) 246 torr
D) 346 torr
E) 400. torr

F) C) and E)
G) B) and E)

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Carbon tetrachloride, once widely used in fire extinguishers and as a dry cleaning fluid, has been found to cause liver damage to those exposed to its vapors over long periods of time. What is the boiling point of a solution prepared by dissolving 375 g of sulfur (S8, Carbon tetrachloride, once widely used in fire extinguishers and as a dry cleaning fluid, has been found to cause liver damage to those exposed to its vapors over long periods of time. What is the boiling point of a solution prepared by dissolving 375 g of sulfur (S<sub>8</sub>,   = 256.5 g/mol)  in 1250 g of CCl<sub>4</sub>? K<sub>b</sub> = 5.05°C/m, boiling point of pure CCl<sub>4 </sub>= 76.7°C? A)  70.8°C B)  75.2°C C)  78.2°C D)  82.6°C E)  >85°C = 256.5 g/mol) in 1250 g of CCl4? Kb = 5.05°C/m, boiling point of pure CCl4 = 76.7°C?


A) 70.8°C
B) 75.2°C
C) 78.2°C
D) 82.6°C
E) >85°C

F) A) and E)
G) None of the above

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Electrolyte solutions generally behave less ideally as the solute concentration increases.

A) True
B) False

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From the following list of aqueous solutions and water, select the one with the lowest freezing point.


A) 0.75 m (NH4) 3PO4
B) 1.0 m CaSO4
C) 1.0 m LiClO4
D) 1.5 m CH3OH, methyl alcohol
E) pure water

F) C) and D)
G) A) and E)

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A

A solution of ethanol (C2H6O) in water is sometimes used as a disinfectant. 1.00 L of this solution contains 553 g of ethanol and 335 g of water. What is the molality of the ethanol in this solution?


A) 0.392 m
B) 0.608 m
C) 13.5 m
D) 33.6 m
E) 35.8 m

F) B) and E)
G) A) and B)

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The most abundant molecules in the cell membranes of most species are


A) proteins.
B) sugars.
C) phospholipids.
D) fatty acids.
E) steroids.

F) A) and B)
G) A) and C)

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A 0.89% (w/v) sodium chloride solution is referred to as physiological saline solution because it has the same concentration of salts as human blood. What is the molarity of a physiological saline solution?


A) 0.0028 M
B) 0.015 M
C) 0.15 M
D) 0.30 M
E) 0.35 M

F) A) and B)
G) B) and D)

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Two aqueous are prepared: 1.00 m Na2CO3 and 1.00 m LiCl. Which of the following statements is true?


A) The Na2CO3 solution has a higher osmotic pressure and higher vapor pressure than the LiCl solution.
B) The Na2CO3 solution has a higher osmotic pressure and higher boiling point than the LiCl solution.
C) The Na2CO3 solution has a lower osmotic pressure and lower vapor pressure than the LiCI solution.
D) The Na2CO3 solution has a lower osmotic pressure and higher boiling point than the LiCl solution.
E) None of the above statements is true.

F) A) and E)
G) A) and C)

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Cinnamaldehyde ( Cinnamaldehyde (   = 132.15 g/mol)  is used as a flavoring agent. What mass of cinnamaldehyde must be added to 175 g of ethanol to give a solution whose boiling point is 82.7°C? K<sub>b</sub> = 1.22°C/m, boiling point of pure ethanol = 78.5°C A)  62.4 g B)  67.8 g C)  76.2 g D)  78.5 g E)  79.6 g = 132.15 g/mol) is used as a flavoring agent. What mass of cinnamaldehyde must be added to 175 g of ethanol to give a solution whose boiling point is 82.7°C? Kb = 1.22°C/m, boiling point of pure ethanol = 78.5°C


A) 62.4 g
B) 67.8 g
C) 76.2 g
D) 78.5 g
E) 79.6 g

F) A) and D)
G) A) and E)

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What concentration of aqueous FeCl3 would have the same osmotic pressure as a 0.20 M solution of CaCl2 at the same temperature, assuming ideal behavior?


A) 0.60 M
B) 0.40 M
C) 0.30 M
D) 0.15 M
E) 0.10 M

F) C) and D)
G) B) and E)

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D

Saccharin, one of the first non-nutritive sweeteners used in soft-drinks, is 500 times sweeter than sugar in dilute aqueous solutions. The solubility of saccharin is 1.00 gram per 290 mL of solution. What is the molarity of a saturated saccharin solution? ( Saccharin, one of the first non-nutritive sweeteners used in soft-drinks, is 500 times sweeter than sugar in dilute aqueous solutions. The solubility of saccharin is 1.00 gram per 290 mL of solution. What is the molarity of a saturated saccharin solution? (   <sub>saccharin</sub> = 183.2 g/mol)  A)  0.0188 M B)  0.632 M C)  1.58 M D)  3.45 M E)  none of the above saccharin = 183.2 g/mol)


A) 0.0188 M
B) 0.632 M
C) 1.58 M
D) 3.45 M
E) none of the above

F) B) and E)
G) All of the above

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A

Ideal solutions do not conform to Raoult's Law.

A) True
B) False

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Which of the following pairs of ions is arranged so that the ion with the larger (i.e., more negative) heat of hydration is listed first?


A) Br-, K+
B) Mg2+, Sr 2+
C) Ca2+, Sc3+
D) Na+, Li+
E) None of the above are arranged in this way.

F) A) and B)
G) All of the above

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