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Which is the best acid to prepare a buffer with the lowest pH?


A) C5H5O5COOH,Ka = 4.0 × 10-6
B) HOC6H4OCOOH,Ka = 1.0 × 10-3
C) HBrO,Ka = 2.3 × 10-9
D) C6H4(COOH) 2,Ka = 2.9 × 10-4
E) CH3COOH,Ka = 1.8 × 10-5

F) B) and E)
G) A) and B)

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What molar ratio of CH3COOH to CH3COONa should be used in order to prepare an acetic acid / sodium acetate buffer solution with a pH of 4.00 ± 0.02? [Ka(CH3COOH) = 1.8 × 10-5]


A) 0.18
B) 0.84
C) 1.2
D) 5.6
E) 0.10

F) A) and E)
G) A) and D)

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The molar solubility of tin(II) iodide is 1.28 × 10-2 mol/L.What is Ksp for this compound?


A) 8.39 × 10-6
B) 1.28 × 10-2
C) 4.20 × 10-6
D) 1.64 × 10-4
E) 2.10 × 10-6

F) A) and B)
G) B) and D)

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When an acid,HA,is titrated with 0.1 M NaOH,the pH at the half equivalence point of the titration is 4.5.What is the Ka of the acid?


A) 3.2 x 10-5
B) 3.2 x 10-10
C) 1.8 x 10-3
D) 7.0 x 10-7
E) HA is a strong acid

F) B) and E)
G) B) and C)

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Indicators are weak acids that are one color in acidic solution and another color in basic solution.

A) True
B) False

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Which of the following acids is the best acid to prepare a buffer with the highest pH?


A) C5H5O5COOH,Ka = 4.0 × 10-6
B) HOC6H4OCOOH,Ka = 1.0 × 10-3
C) HBrO,Ka = 2.3 × 10-9
D) C6H4(COOH) 2,Ka = 2.9 × 10-4
E) CH3COOH,Ka = 1.8 × 10-5

F) D) and E)
G) All of the above

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Increasing the concentrations of the components of a buffer solution will increase the buffer range.

A) True
B) False

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Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III) fluoride.[Ksp(CrF3) = 6.6 × 10-11]


A) 0.023 M
B) 0.032 M
C) 7.7 × 10-8 M
D) 2.9 × 10-9 M
E) 6.9 × 10-10 M

F) A) and B)
G) B) and D)

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What is the pH of a solution prepared by mixing 500.mL of 0.10 M NaOCl and 500.mL of 0.20 M HOCl? [Ka(HOCl) = 3.2 × 10-8]


A) 4.10
B) 7.00
C) 7.19
D) 7.49
E) 7.80

F) A) and E)
G) A) and B)

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Which will precipitate first when AgNO3 is added to a solution containing equal concentrations of Br-,Cl-, and I- ions?


A) AgBr
B) AgCl
C) AgI
D) AgNO3
E) No precipitate will form

F) A) and E)
G) B) and D)

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A 10.0-mL sample of 0.75 M CH3CH2COOH is titrated with 0.30 M NaOH.What is the pH of the solution after 22.0 mL of NaOH have been added to the acid? [Ka(CH3CH2COOH) = 1.3 × 10-5]


A) 5.75
B) 4.94
C) 4.83
D) 4.02
E) 3.95

F) D) and E)
G) B) and C)

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If the pH of a buffer solution is greater than the pKa value of the buffer acid,the buffer will have more capacity to neutralize added base than added acid.

A) True
B) False

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Which of the following is correct for the equivalence point in an acid-base titration?


A) The pH is at its highest value for any reaction.
B) The amounts of acid and base combined are in a stoichiometric ratio at the equivalence point in an acid-base titration.
C) The pH is 7.0.
D) The pH is equal to the pKa of the weak acid.
E) The pH is equal to the pKb of the weak base.

F) A) and B)
G) A) and C)

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The ____________________ is the point in a titration where the color of the indicator changes.

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Calculate the solubility of silver oxalate,Ag2C2 O4,in pure water. [Ksp(Ag2C2O4) = 1.0 × 10-11]


A) 1.4 × 10-4 M
B) 8.2 × 10-5 M
C) 5.4 × 10-5 M
D) 3.2 × 10-6 M
E) 2.5 × 10-12 M

F) A) and E)
G) A) and D)

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What is the effect on the equilibrium when sodium formate is added to a solution of formic acid? HCOOH(aq) What is the effect on the equilibrium when sodium formate is added to a solution of formic acid? HCOOH(aq)    H<sup>+</sup>(aq) + HCOO<sup>-</sup>(aq)  A) There is no change in the equilibrium. B) The equilibrium shifts to the right. C) More information is needed to answer the question. D) The equilibrium shifts to the left. E) The pH decreases. H+(aq) + HCOO-(aq)


A) There is no change in the equilibrium.
B) The equilibrium shifts to the right.
C) More information is needed to answer the question.
D) The equilibrium shifts to the left.
E) The pH decreases.

F) A) and C)
G) B) and C)

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When a strong acid is titrated with a strong base,the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is between 3.5 and 7.0.
D) is equal to the p Ka of the acid.
E) is equal to 3.5.

F) A) and E)
G) A) and B)

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Methyl red is a common acid-base indicator.It has a Ka equal to 6.3 × 10-6.Its un-ionized form is red and its anionic form is yellow.What color would a methyl red solution have at pH = 7.8?


A) green
B) red
C) blue
D) yellow
E) violet

F) A) and E)
G) C) and D)

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Calculate the solubility of zinc hydroxide,Zn(OH) 2,in 1.00 M NaOH.Ksp = 3.0 × 10-16 for Zn(OH) 2,Kf = 3.0 × 1015 for Zn(OH) 42-


A) 0.60 M
B) 0.52 M
C) 0.37 M
D) 0.32 M
E) 0.24 M

F) C) and E)
G) A) and B)

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A 50.0-mL sample of 0.50 M HCl is titrated with 0.50 M NaOH.What is the pH of the solution after 28.0 mL of NaOH have been added to the acid?


A) 0.85
B) 2.96
C) 2.85
D) 1.49
E) 3.81

F) B) and C)
G) A) and C)

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