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A solution of sodium acetate (CH3COONa)in water is weakly basic.

A) True
B) False

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The most basic oxides are formed from elements found in the __________________ region of the periodic table.


A) upper right
B) upper left
C) center
D) lower right
E) lower left

F) A) and B)
G) B) and C)

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A 0.15 M solution of chloroacetic acid has a pH of 1.86.What is the value of Ka for this acid?


A) 7.2 × 101
B) 1.6 × 10-1
C) 9.9 × 10-2
D) 1.4 × 10-3
E) 2.7 × 10-4

F) A) and B)
G) B) and E)

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What is the conjugate base of NH3?


A) NH2
B) NH2+
C) NH2-
D) NH4
E) NH4+

F) D) and E)
G) A) and E)

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Picric acid has been used in the leather industry and in etching copper.However,its laboratory use has been restricted because it dehydrates on standing and can become shock sensitive.It has an acid dissociation constant of 0.42.What is the [H3O+] for a 0.20 M solution of picric acid?


A) 0.022 M
B) 0.052 M
C) 0.15 M
D) 0.20 M
E) 0.29 M

F) A) and E)
G) D) and E)

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Calculate the concentration of malonate ion (C3H2O42-) in a 0.200 M solution of malonic acid (C3H4O4) .(For malonic acid,Ka1 = 1.4 × 10-3,Ka2 = 2.0 × 10-6.)


A) 2.8 × 10-4 M
B) 0.016 M
C) 1.8 × 10-4 M
D) 1.4 × 10-3 M
E) 2.0 × 10-6 M

F) All of the above
G) A) and E)

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The first ionization constant Ka1 is always smaller than the second ionization constant Ka2 for the ionization of a diprotic acid.

A) True
B) False

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Which is a basic oxide?


A) CO2
B) MgO
C) As2O3
D) SO2
E) Cl2O7

F) C) and E)
G) All of the above

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Amphoteric oxides exhibit both acidic and basic properties.

A) True
B) False

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Calculate the pH of a 0.021 M NaCN solution.[Ka(HCN) = 4.9 × 10-10]


A) 1.68
B) 3.19
C) 4.69
D) 9.31
E) 10.81

F) A) and C)
G) B) and C)

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What is [OH-] for a solution at 25°C that has [H3O+] = 8.23 × 10-2 M?


A) 8.23 × 10-2 M
B) 1.22 × 10-6 M
C) 8.23 × 10-12 M
D) 1.22 × 10-13 M
E) 8.23 × 10-16 M

F) A) and D)
G) A) and E)

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Which is an acidic oxide?


A) P4O10
B) MgO
C) Fe2O3
D) K2O
E) Cr2O3

F) A) and B)
G) C) and D)

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Below is a representation of pure liquid HX,an amphoteric substance,at equilibrium.(Each circle represents 1.0 ×10-3 mol of atoms,and the volume of the box is 1.0 L.) Below is a representation of pure liquid HX,an amphoteric substance,at equilibrium.(Each circle represents 1.0 ×10<sup>-</sup><sup>3</sup> mol of atoms,and the volume of the box is 1.0 L.)    What is the autoionization constant for HX? A) 4.9 ×10<sup>-</sup><sup>2</sup> B) 4.0 ×10<sup>-</sup><sup>3</sup> C) 4.4 ×10<sup>-</sup><sup>4</sup> D) 4.0 ×10<sup>-</sup><sup>6</sup> E) 2.5 ×10<sup>5</sup> What is the autoionization constant for HX?


A) 4.9 ×10-2
B) 4.0 ×10-3
C) 4.4 ×10-4
D) 4.0 ×10-6
E) 2.5 ×105

F) B) and C)
G) D) and E)

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Acid strength decreases in the series HI > HSO4-> HF > HCN.Which of these anions is the weakest base?


A) I-
B) SO42-
C) F-
D) CN-

E) C) and D)
F) A) and B)

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The following is the correct order for the acid strength for these oxoacids.HClO > HClO2 > HClO3> HClO4

A) True
B) False

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Equal volumes of two solutions,one containing a strong acid at pH 2 and the other containing a strong base at pH 12,are mixed.Once equilibrium is achieved,what is the final pH of the combined solution?


A) 6
B) 7
C) 10
D) 14
E) 24

F) All of the above
G) D) and E)

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Which of the following is the correct Kb expression for the reaction below? B(aq) + H2O (l) Which of the following is the correct Kb expression for the reaction below? B(aq) + H<sub>2</sub>O (l)    HB+(aq) + OH<sup>-</sup>(aq)  A) K<sub>b</sub> = [B][ H<sub>2</sub>O] B)    C)    D)    E) K<sub>b</sub> = [HB<sup>+</sup>][OH<sup>-</sup>] HB+(aq) + OH-(aq)


A) Kb = [B][ H2O]
B) Which of the following is the correct Kb expression for the reaction below? B(aq) + H<sub>2</sub>O (l)    HB+(aq) + OH<sup>-</sup>(aq)  A) K<sub>b</sub> = [B][ H<sub>2</sub>O] B)    C)    D)    E) K<sub>b</sub> = [HB<sup>+</sup>][OH<sup>-</sup>]
C) Which of the following is the correct Kb expression for the reaction below? B(aq) + H<sub>2</sub>O (l)    HB+(aq) + OH<sup>-</sup>(aq)  A) K<sub>b</sub> = [B][ H<sub>2</sub>O] B)    C)    D)    E) K<sub>b</sub> = [HB<sup>+</sup>][OH<sup>-</sup>]
D) Which of the following is the correct Kb expression for the reaction below? B(aq) + H<sub>2</sub>O (l)    HB+(aq) + OH<sup>-</sup>(aq)  A) K<sub>b</sub> = [B][ H<sub>2</sub>O] B)    C)    D)    E) K<sub>b</sub> = [HB<sup>+</sup>][OH<sup>-</sup>]
E) Kb = [HB+][OH-]

F) C) and D)
G) A) and B)

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Since zirconium is a metal,ZrO2 is expected to be a/an _____ oxide.


A) acidic
B) ionic
C) amphoteric
D) neutral
E) basic

F) D) and E)
G) B) and D)

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The ammonium ion,NH4+,is a weak acid.

A) True
B) False

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Which is a Lewis acid but not a Brønsted acid?


A) HCN
B) CO32-
C) OH-
D) Cl-
E) Al3+

F) B) and E)
G) D) and E)

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