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Find the pH of a 0.135 M aqueous solution of periodic acid (HIO4) ,for which Ka = 2.3 × 10-2.


A) 1.25
B) 3.28
C) 1.17
D) 1.34
E) 1.64

F) A) and D)
G) A) and C)

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A(n)_______________ can be added to a solution to increase the pH of the solution.

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Identify the conjugate base of HPO42- in the reaction HCO3- + HPO42- Identify the conjugate base of HPO<sub>4</sub><sup>2-</sup> in the reaction HCO<sub>3</sub><sup>-</sup> + HPO<sub>4</sub><sup>2-</sup> <sup> </sup>   H<sub>2</sub>CO<sub>3</sub> + PO<sub>4</sub><sup>3-</sup> A) H<sub>2</sub>O B) HCO<sub>3</sub><sup>-</sup> C) H<sub>2</sub>CO<sub>3</sub> D) PO<sub>4</sub><sup>3-</sup> E) None of these H2CO3 + PO43-


A) H2O
B) HCO3-
C) H2CO3
D) PO43-
E) None of these

F) B) and E)
G) B) and D)

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Which is the formula for the hydronium ion?


A) OH-
B) H2O
C) H3O+
D) H3O-
E) H2O +

F) None of the above
G) All of the above

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What is the name given to a substance that can act as a Brønsted acid or as a Brønsted base according to what it is reacting with?


A) hydrophilic
B) hydrophobic
C) amphoteric
D) isoprotic
E) isoelectronic

F) C) and E)
G) A) and E)

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Calcium oxide,CaO,also known as quick lime,may react with carbon dioxide to form calcium carbonate,CaCO3.Which acts as a Lewis acid in the reaction?


A) Ca2+
B) O2-
C) CO2
D) CaCO3
E) CO32-

F) A) and B)
G) B) and C)

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Which of the following salts will form an acidic solution when dissolved in water?


A) NaCl
B) NaNO2
C) NH4NO3
D) NH4CN

E) A) and D)
F) A) and C)

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In the reaction,HSO4-(aq) + OH-(aq) In the reaction,HSO<sub>4</sub><sup>-</sup>(aq) + OH<sup>-</sup>(aq)    SO<sub>4</sub><sup>2-</sup>(aq) + H<sub>2</sub>O (l) ,the conjugate acid-base pairs are pair 1 pair 2 A) HSO<sub>4</sub><sup>-</sup> and SO<sub>4</sub><sup>2</sup><sup>-</sup>; H<sub>2</sub>O and OH<sup>-</sup>. B) HSO<sub>4</sub><sup>-</sup> and H<sub>3</sub>O<sup>+</sup>; SO<sub>4</sub><sup>2</sup> <sup>-</sup> and OH<sup>-</sup>. C) HSO<sub>4</sub><sup>-</sup> and OH<sup>-</sup>; SO<sub>4</sub><sup>2</sup> <sup>-</sup> and H<sub>2</sub>O. D) HSO<sub>4</sub><sup>-</sup> and H<sub>2</sub>O; OH <sup>-</sup> and SO<sub>4</sub><sup>2</sup><sup>-</sup>. E) HSO<sub>4</sub><sup>-</sup> and OH<sup>-</sup>; SO<sub>4</sub><sup>2</sup> <sup>-</sup> and H<sub>3</sub>O<sup>+</sup>. SO42-(aq) + H2O (l) ,the conjugate acid-base pairs are pair 1 pair 2


A) HSO4- and SO42-; H2O and OH-.
B) HSO4- and H3O+; SO42 - and OH-.
C) HSO4- and OH-; SO42 - and H2O.
D) HSO4- and H2O; OH - and SO42-.
E) HSO4- and OH-; SO42 - and H3O+.

F) A) and C)
G) C) and D)

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What mass of sodium nitrite must be added to enough water to make 350.0 mL of a solution with pH = 8.40? [Ka(HNO2) = 5.6 × 10-4]


A) 68 g
B) 1.7 × 10-4 g
C) 0.039 g
D) 8.7 g
E) 24 g

F) A) and D)
G) A) and B)

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What is the pOH of a 0.0085 M KOH solution?


A) 2.07
B) 4.85
C) 9.15
D) 11.93
E) 0.0085

F) A) and D)
G) A) and C)

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The stronger the acid,the weaker its conjugate base.

A) True
B) False

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Which is the strongest acid?


A) HBrO3
B) HClO
C) HBrO2
D) HBrO
E) HClO3

F) A) and B)
G) A) and E)

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Which statement is true regarding the reversible reaction below? H2CO3+ F- Which statement is true regarding the reversible reaction below? H<sub>2</sub>CO<sub>3</sub>+ F<sup>-</sup>   HCO<sub>3</sub>+ HF.K<sub>a</sub>1(H<sub>2</sub>CO<sub>3</sub>) = 4.2 × 10<sup>-</sup><sup>7</sup>; K<sub>a</sub>(HF) = 7.1 × 10<sup>-</sup><sup>4</sup> A) At equilibrium,[HF] > [H<sub>2</sub>CO<sub>3</sub>] because HF is a stronger acid than H<sub>2</sub>CO<sub>3</sub>. B) At equilibrium,[HF] > [H<sub>2</sub>CO<sub>3</sub>] because H<sub>2</sub>CO<sub>3</sub> is a stronger acid than HF. C) At equilibrium,[HF] = [H<sub>2</sub>CO<sub>3</sub>]. D) At equilibrium,[H<sub>2</sub>CO<sub>3</sub>] > [HF] because HF is a stronger acid than H<sub>2</sub>CO<sub>3</sub>. E) At equilibrium,[H<sub>2</sub>CO<sub>3</sub>] > [HF] because H<sub>2</sub>CO<sub>3</sub> is a stronger acid than HF. HCO3+ HF.Ka1(H2CO3) = 4.2 × 10-7; Ka(HF) = 7.1 × 10-4


A) At equilibrium,[HF] > [H2CO3] because HF is a stronger acid than H2CO3.
B) At equilibrium,[HF] > [H2CO3] because H2CO3 is a stronger acid than HF.
C) At equilibrium,[HF] = [H2CO3].
D) At equilibrium,[H2CO3] > [HF] because HF is a stronger acid than H2CO3.
E) At equilibrium,[H2CO3] > [HF] because H2CO3 is a stronger acid than HF.

F) D) and E)
G) A) and C)

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Since arsenic is a nonmetal,As2O3 is expected to be a/an _____ oxide.


A) acidic
B) ionic
C) amphoteric
D) neutral
E) basic

F) A) and B)
G) A) and C)

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What is the pH of a 0.20 M solution of NH4Cl? [Kb(NH3) = 1.8 × 10-5]


A) 3.74
B) 4.98
C) 6.53
D) 9.02
E) 11.28

F) C) and E)
G) A) and E)

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A solution is prepared by adding 0.10 mol of iron(III) nitrate,Fe(NO3) 3,to 1.00 L of water.Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The value of Ka for the species in solution must be known before a prediction can be made.
E) The value of Kb for the species in solution must be known before a prediction can be made.

F) B) and D)
G) C) and D)

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Formic acid,which is a component of some insect venoms,has a Ka = 1.8 × 10-4.What is the [H3O+] in a solution that is initially 0.10 M formic acid,HCOOH?


A) 4.2 × 10-3 M
B) 8.4 × 10-3 M
C) 1.8 × 10-4 M
D) 1.8 × 10-5 M
E) 1.8 × 10-6 M

F) None of the above
G) A) and B)

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What is the value of Kb for the cyanide anion,CN-? Ka(HCN) = 6.2 × 10-10


A) 1.6 × 10-4
B) 1.6 × 10-5
C) 3.8 × 10-4
D) 3.8 × 10-5
E) 6.2 × 104

F) A) and D)
G) C) and E)

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Which is the strongest acid?


A) SO42-
B) H2SO3
C) H2SO4
D) HSO4-
E) HSO3-

F) B) and C)
G) All of the above

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Iodine trichloride,ICl3,will react with a chloride ion to form ICl4-.Which acts as a Lewis acid this reaction?


A) ICl4-
B) ICl3
C) Cl-
D) I3+
E) The solvent

F) None of the above
G) B) and D)

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