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At 35ºC,the equilibrium constant for the reaction 2NOCl(g) At 35ºC,the equilibrium constant for the reaction 2NOCl(g)    2NO(g) + Cl<sub>2</sub>(g) is K<sub>c</sub> = 1.6×10<sup>-5</sup>.An equilibrium mixture was found to have the following concentrations of Cl<sup>2</sup> and NOCl: [Cl<sub>2</sub>] = 1.2 × 10<sup>-2</sup> M; [NOCl] = 2.8 ×10<sup>-1</sup> M.Calculate the concentration of NO(g) at equilibrium. A) 1.0 × 10<sup>-4</sup> M B) 1.0 × 10<sup>-2</sup> M C) 2.8 × 10<sup>-1</sup> M D) 2.4 × 10<sup>-2</sup> M E) 1.6 × 10<sup>-3</sup> M 2NO(g) + Cl2(g) is Kc = 1.6×10-5.An equilibrium mixture was found to have the following concentrations of Cl2 and NOCl: [Cl2] = 1.2 × 10-2 M; [NOCl] = 2.8 ×10-1 M.Calculate the concentration of NO(g) at equilibrium.


A) 1.0 × 10-4 M
B) 1.0 × 10-2 M
C) 2.8 × 10-1 M
D) 2.4 × 10-2 M
E) 1.6 × 10-3 M

F) D) and E)
G) B) and C)

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At 25°C,the equilibrium constant,Kc,for the reaction 2A(g) At 25°C,the equilibrium constant,K<sub>c</sub>,for the reaction 2A(g)    B(g) + C(g) is 0.0350. A mixture of 8.00 moles of B and 12.00 moles of C in a 20.0-L container is allowed to come to equilibrium.What is the equilibrium concentration of A? A) 0.339 M B) 0.378 M C) 0.400 M D) 0.677 M E) 0.755 M B(g) + C(g) is 0.0350. A mixture of 8.00 moles of B and 12.00 moles of C in a 20.0-L container is allowed to come to equilibrium.What is the equilibrium concentration of A?


A) 0.339 M
B) 0.378 M
C) 0.400 M
D) 0.677 M
E) 0.755 M

F) A) and B)
G) B) and E)

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Consider the following reactions and their associated equilibrium constants: A + 2B Consider the following reactions and their associated equilibrium constants: A + 2B   C K<sub>1</sub> C   D + E K<sub>2</sub> For the reaction A + 2B   D + E,having equilibrium constant K<sub>c</sub>, A) K<sub>c</sub> = K<sub>1</sub> + K<sub>2</sub>. B) K<sub>c</sub> = K<sub>1</sub>/K<sub>2</sub>. C) K<sub>c</sub> = K<sub>1</sub> - K<sub>2</sub>. D) K<sub>c</sub> = (K<sub>1</sub>) (K<sub>2</sub>) . E) K<sub>c</sub> = K<sub>2</sub>/K<sub>1</sub>. C K1 C Consider the following reactions and their associated equilibrium constants: A + 2B   C K<sub>1</sub> C   D + E K<sub>2</sub> For the reaction A + 2B   D + E,having equilibrium constant K<sub>c</sub>, A) K<sub>c</sub> = K<sub>1</sub> + K<sub>2</sub>. B) K<sub>c</sub> = K<sub>1</sub>/K<sub>2</sub>. C) K<sub>c</sub> = K<sub>1</sub> - K<sub>2</sub>. D) K<sub>c</sub> = (K<sub>1</sub>) (K<sub>2</sub>) . E) K<sub>c</sub> = K<sub>2</sub>/K<sub>1</sub>. D + E K2 For the reaction A + 2B Consider the following reactions and their associated equilibrium constants: A + 2B   C K<sub>1</sub> C   D + E K<sub>2</sub> For the reaction A + 2B   D + E,having equilibrium constant K<sub>c</sub>, A) K<sub>c</sub> = K<sub>1</sub> + K<sub>2</sub>. B) K<sub>c</sub> = K<sub>1</sub>/K<sub>2</sub>. C) K<sub>c</sub> = K<sub>1</sub> - K<sub>2</sub>. D) K<sub>c</sub> = (K<sub>1</sub>) (K<sub>2</sub>) . E) K<sub>c</sub> = K<sub>2</sub>/K<sub>1</sub>. D + E,having equilibrium constant Kc,


A) Kc = K1 + K2.
B) Kc = K1/K2.
C) Kc = K1 - K2.
D) Kc = (K1) (K2) .
E) Kc = K2/K1.

F) B) and E)
G) D) and E)

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Equilibrium constants are known for the following reactions: S(s)+ (3/2)O2(g) Equilibrium constants are known for the following reactions: S(s)+ (3/2)O2(g)   SO<sub>3</sub>(g)K<sub>c</sub> = 9.2 × 10<sup>23</sup> SO<sub>3</sub>(g)   SO<sub>2</sub>(g)+ (1/2)O<sub>2</sub>(g)K<sub>c</sub> = 4.8 × 10<sup>-4</sup> Thus,for the reaction S(s)+ O<sub>2</sub>(g)   SO<sub>2</sub>(g),K<sub>c</sub> = 4.4 × 10<sup>20</sup>. SO3(g)Kc = 9.2 × 1023 SO3(g) Equilibrium constants are known for the following reactions: S(s)+ (3/2)O2(g)   SO<sub>3</sub>(g)K<sub>c</sub> = 9.2 × 10<sup>23</sup> SO<sub>3</sub>(g)   SO<sub>2</sub>(g)+ (1/2)O<sub>2</sub>(g)K<sub>c</sub> = 4.8 × 10<sup>-4</sup> Thus,for the reaction S(s)+ O<sub>2</sub>(g)   SO<sub>2</sub>(g),K<sub>c</sub> = 4.4 × 10<sup>20</sup>. SO2(g)+ (1/2)O2(g)Kc = 4.8 × 10-4 Thus,for the reaction S(s)+ O2(g) Equilibrium constants are known for the following reactions: S(s)+ (3/2)O2(g)   SO<sub>3</sub>(g)K<sub>c</sub> = 9.2 × 10<sup>23</sup> SO<sub>3</sub>(g)   SO<sub>2</sub>(g)+ (1/2)O<sub>2</sub>(g)K<sub>c</sub> = 4.8 × 10<sup>-4</sup> Thus,for the reaction S(s)+ O<sub>2</sub>(g)   SO<sub>2</sub>(g),K<sub>c</sub> = 4.4 × 10<sup>20</sup>. SO2(g),Kc = 4.4 × 1020.

A) True
B) False

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If Q<K then less reactants are observed as the reaction proceeds to ___________.

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What is the expression for the partial pressure of "A" for the following reaction under ideal conditions? A(g) What is the expression for the partial pressure of  A  for the following reaction under ideal conditions? A(g)    B(g)  A) PA = n<sub>A</sub>RT B) PA = (n<sub>A</sub>/V) RT C) PA = V/n<sub>A</sub> D) PA = VRT E) PA = (V/n<sub>A</sub>) RT B(g)


A) PA = nART
B) PA = (nA/V) RT
C) PA = V/nA
D) PA = VRT
E) PA = (V/nA) RT

F) B) and D)
G) All of the above

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At 340.K,KP = 69 for the reaction H2(g) + I2(g) At 340.K,K<sub>P</sub> = 69 for the reaction H<sub>2</sub>(g) + I<sub>2</sub>(g)    2HI(g) .Suppose 50.0 g of HI is injected into an evacuated 5.00-L rigid cylinder at 340.K.What is the total pressure inside the cylinder when the system comes to equilibrium? A) 2.60 atm B) 1.76 atm C) 0.424 atm D) 2.18 atm E) 0.171 atm 2HI(g) .Suppose 50.0 g of HI is injected into an evacuated 5.00-L rigid cylinder at 340.K.What is the total pressure inside the cylinder when the system comes to equilibrium?


A) 2.60 atm
B) 1.76 atm
C) 0.424 atm
D) 2.18 atm
E) 0.171 atm

F) A) and C)
G) C) and E)

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A 6.0-L vessel was found to contain 1.0 mol BrCl3,2.0 mol Br2 and 6.0 mol Cl2. What is the equilibrium constant,Kc,for this equilibrium mixture for the reaction 2BrCl3(g) A 6.0-L vessel was found to contain 1.0 mol BrCl<sub>3</sub>,2.0 mol Br<sub>2</sub> and 6.0 mol Cl<sub>2</sub>. What is the equilibrium constant,K<sub>c</sub>,for this equilibrium mixture for the reaction 2BrCl<sub>3</sub>(g)    Br<sub>2</sub>(g) + 3Cl<sub>2</sub>(g) ? A) 0.014 B) 108 C) 18 D) 12 E) 432 Br2(g) + 3Cl2(g) ?


A) 0.014
B) 108
C) 18
D) 12
E) 432

F) A) and C)
G) A) and B)

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The equilibrium constant,KP,for the reaction H2(g) + I2(g) The equilibrium constant,K<sub>P</sub>,for the reaction H<sub>2</sub>(g) + I<sub>2</sub>(g)    2HI(g) is 55.2 at 425°C.A rigid cylinder at that temperature contains 0.127 Atm of hydrogen,0.134 atm of iodine,and 1.055 atm of hydrogen iodide.Is the system at equilibrium? A) Yes. B) No,the forward reaction must proceed to establish equilibrium. C) No,the reverse reaction must proceed to establish equilibrium. D) I need to know the volume of the container before deciding. E) Need to know the starting pressures of all substances before deciding. 2HI(g) is 55.2 at 425°C.A rigid cylinder at that temperature contains 0.127 Atm of hydrogen,0.134 atm of iodine,and 1.055 atm of hydrogen iodide.Is the system at equilibrium?


A) Yes.
B) No,the forward reaction must proceed to establish equilibrium.
C) No,the reverse reaction must proceed to establish equilibrium.
D) I need to know the volume of the container before deciding.
E) Need to know the starting pressures of all substances before deciding.

F) A) and C)
G) A) and D)

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For the nitrogen fixation reaction,3H2(g) + N2(g) For the nitrogen fixation reaction,3H<sub>2</sub>(g) + N<sub>2</sub>(g)    2NH<sub>3</sub>(g) ,K<sub>c</sub> = 6.0 × 10<sup>-2</sup> at 500°C.If 0.250 M H<sub>2</sub> and 0.050 M NH<sub>3</sub> are present at equilibrium,what is the equilibrium concentration of N<sub>2</sub>? A) 3.3 M B) 2.7 M C) 0.20 M D) 0.083 M E) 0.058 M 2NH3(g) ,Kc = 6.0 × 10-2 at 500°C.If 0.250 M H2 and 0.050 M NH3 are present at equilibrium,what is the equilibrium concentration of N2?


A) 3.3 M
B) 2.7 M
C) 0.20 M
D) 0.083 M
E) 0.058 M

F) C) and E)
G) C) and D)

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For the following reaction at equilibrium,which one of the changes below would cause the equilibrium to shift to the left? 2NOBr(g) For the following reaction at equilibrium,which one of the changes below would cause the equilibrium to shift to the left? 2NOBr(g)    2NO(g) + Br<sub>2</sub>(g) ,ΔHº<sub>rxn</sub> = 30 kJ/mol A) Increase the container volume B) Remove some NO C) Remove some Br<sub>2</sub> D) Add more NOBr E) Decrease the temperature 2NO(g) + Br2(g) ,ΔHºrxn = 30 kJ/mol


A) Increase the container volume
B) Remove some NO
C) Remove some Br2
D) Add more NOBr
E) Decrease the temperature

F) D) and E)
G) A) and B)

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A change in the temperature can change the value of the equilibrium constant.

A) True
B) False

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The formation constant for the reaction Ag+(aq) + 2NH3(aq) The formation constant for the reaction Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)  Is K<sub>f</sub> = 1.7 × 10<sup>7</sup> at 25°C.What is ΔG° at this temperature? (R = 8.314 J/K• mol)  A) -1.5 kJ/mol B) -3.5 kJ/mol C) -18 kJ/mol D) -23 kJ/mol E) -41 kJ/mol Ag(NH3) 2+(aq) Is Kf = 1.7 × 107 at 25°C.What is ΔG° at this temperature? (R = 8.314 J/K• mol)


A) -1.5 kJ/mol
B) -3.5 kJ/mol
C) -18 kJ/mol
D) -23 kJ/mol
E) -41 kJ/mol

F) B) and C)
G) B) and E)

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For the reaction HCONH2(g) For the reaction HCONH<sub>2</sub>(g)    NH<sub>3</sub>(g) + CO(g) ,K<sub>c</sub> = 4.84 at 400 K.If ΔH° for this reaction is 29 kJ/mol,find K<sub>c</sub> at 500 K. A) 5.8 B) 0.17 C) 27.5 D) 0.88 E) 10.3 NH3(g) + CO(g) ,Kc = 4.84 at 400 K.If ΔH° for this reaction is 29 kJ/mol,find Kc at 500 K.


A) 5.8
B) 0.17
C) 27.5
D) 0.88
E) 10.3

F) None of the above
G) A) and D)

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Consider the reaction: 2A(g) + B(g) → 2C(g) If ΔG° = 50.0 kJ/mol at T = 25°C and PA = PB = 1 atm and PC = 2 atm,what is the value of ΔG? (R = 8.314 J/K • mol)


A) 50.0 kJ/mol
B) 49.7 kJ/mol
C) 46.5 kJ/mol
D) 53.4 kJ/mol
E) -49.7 kJ/mol

F) C) and D)
G) A) and B)

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