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Krypton has a higher melting point than argon because of its


A) hydrogen bonding.
B) stronger dispersion forces.
C) permanent dipole moment.
D) ionic bonds.
E) greater ionization energy.

F) B) and C)
G) B) and E)

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Identify the dominant (strongest)type of intermolecular force present in Cl2(l).

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For the solid forms of the following elements,which one is most likely to be of the molecular type?


A) Cs
B) C
C) Pb
D) S
E) Cr

F) A) and E)
G) D) and E)

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If a molecule at the surface of a liquid has enough kinetic energy to escape the liquid phase and enter the gas phase,then which of the following terms is used to describe this phenomenon?


A) Boiling point
B) Condensation
C) Vaporization
D) Sublimation
E) Gasification

F) B) and E)
G) A) and E)

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Molecular crystals are held together by the intermolecular forces of dispersion and dipole-dipole forces and by hydrogen bonding.

A) True
B) False

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Which one of the following substances does not exist in the indicated solid type?


A) graphite-covalent crystals
B) Na-metallic crystals
C) SiO2-molecular crystals
D) NaCl-ionic crystals
E) diamond-covalent crystals

F) D) and E)
G) B) and D)

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In a sample of hydrogen iodide,__________________ are the most important intermolecular forces.


A) dipole-dipole forces
B) London dispersion forces
C) hydrogen bonding
D) covalent bonds
E) polar covalent bonds

F) A) and D)
G) A) and C)

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One of the crystalline forms of zinc oxide is a structure where the oxygen atoms are at the lattice points in a face-centered cubic lattice.How many atoms are in each unit cell?


A) 2
B) 4
C) 6
D) 8
E) 10

F) D) and E)
G) A) and B)

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Based on the phase diagram of a pure substance given below,what is the significance of the point labeled B? Based on the phase diagram of a pure substance given below,what is the significance of the point labeled B?   A) It is the normal melting point. B) It is the triple point. C) It is the critical point. D) It is the normal sublimation point. E) It is the normal boiling point.


A) It is the normal melting point.
B) It is the triple point.
C) It is the critical point.
D) It is the normal sublimation point.
E) It is the normal boiling point.

F) A) and E)
G) A) and D)

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At a temperature of 27 K,neon condenses due to


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) covalent bonding.
E) intramolecular forces.

F) B) and E)
G) D) and E)

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The molar enthalpy of vaporization of boron tribromide is 30.5 kJ/mol,and its normal boiling point is 91°C.What is the vapor pressure of BBr3 at 20.°C? (R = 8.314 J/K • mol)


A) 11.5 torr
B) 659 torr
C) 255 torr
D) 66.2 torr
E) 167 torr

F) C) and D)
G) A) and C)

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Which has the highest surface tension at room temperature?


A) CH4
B) CF4
C) CCl4
D) CBr4
E) CI4

F) D) and E)
G) C) and D)

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Helium atoms do not combine to form He2 molecules,yet He atoms do attract one another weakly through


A) dipole-dipole forces.
B) ion-dipole forces.
C) dispersion forces.
D) dipole-induced dipole forces.
E) hydrogen bonding.

F) B) and D)
G) B) and C)

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Which of the following factors can contribute to the viscosity for a liquid?


A) Temperature
B) Hydrogen bonding
C) Molecular entanglements
D) London forces
E) All of the answers are correct.

F) A) and E)
G) B) and E)

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Which of the responses includes all of the following that can form hydrogen bonds with water molecules? I.Na+,II.CH3COOH,III.C2H6,IV.CH3NH2


A) I and II
B) I and III
C) II and III
D) II and IV
E) III and IV

F) C) and D)
G) None of the above

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Liquid sodium can be used as a heat transfer fluid.Its vapor pressure is 40.0 torr at 633°C and 400.0 torr at 823°C.What is its heat of vaporization?


A) 43.4 kJ/mol
B) 52.5 kJ/mol
C) 70.6 kJ/mol
D) 1.00 × 102 kJ/mol
E) 3.64 kJ/mol

F) B) and C)
G) A) and E)

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Which one of the following substances crystallizes as a molecular solid?


A) KI
B) SiO2
C) Sn
D) CH3OH
E) Al2(SO4) 3

F) A) and E)
G) B) and E)

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Identify the dominant (strongest)type of intermolecular force present in NH3(l).

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The atomic planes in a graphite crystal are separated by 335 pm.At what angle would you find the first-order (n = 1) diffraction of 0.154-nm X rays from a graphite crystal?


A) 27.4°
B) 66.8°
C) 0.232°
D) 13.3°
E) 38.0°

F) C) and E)
G) B) and C)

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a.State the essential requirements for hydrogen bonding to be important in a compound. b.List four properties of water which are significantly influenced by the presence of hydrogen bonding. a.The compound must contain hydrogen bonded to an atom which is small,electronegative,and has lone pairs of electrons.The atoms which meet these criteria are N,O,and F.

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b.High specific heat capacity;...

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